ALKEN CLEAR-FLO® 4000

Effective Date: 05/02/2007

 Product Bulletin


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 Material Safety Data Sheet
 Manufacturer's Name: Alken-Murray Corporation
 Manufacturer's Address: P.O. Box 400, New Hyde Park, New York 11040
  T: 540-636-1236 Fax: 540-636-1770
  E-mail: msds@alken-murray.com 
 Manufacturer's Cage Code: 2A384
For chemical emergency - spill, leak, fire or accident - call CHEMTREC - day or night - (800) 424-9300 or outside the USA (703) 527-3887

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NFPA Hazard Ratings:

0=Minimal, 1=Slight, 2=Moderate, 3=Serious, 4=Severe


 Health=1  Fire=1  Reactivity=0

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1. Product Identification

 Synonyms:  None
 CAS Number:  Not applicable to mixtures
 Chemical Formula:  mixture
 Formula ID Codes:  4000

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2. Composition/Information on Ingredients

*Natural dolomitic limestone contains a variable composition, primarily calcium carbonate and magnesium carbonate, but it usually includes 0.1 to 1% each of ferric oxide and crystalline silica (quartz), so Alken-Murray listed BOTH Crystalline silica and Ferric oxide as ingredients in this MSDS.

Ingredients not precisely identified are proprietary and/or non-hazardous per 29 CFR 1910-1200 and/or represent less than 1%. All chemical ingredients appear on the EPA TSCA inventory.

 Chemical Name  CAS Number  OSHA PEL  ACGIH TLV   % Weight
 Wheat bran substrate

 116469-86-4

  NDA

  NDA

 45 - 70
 Water

7732-18-5

 NDA

 NDA

 10 - 15
 Glycerine

  56-81-5 

  NDA

  NDA

  1 - 3
Dolomitic limestone (calcium carbonate, magnesium carbonate and ferric oxide)

 

 

1317-65-3

 

 

 

TWA:15 mg/m3

 

 

 

TWA:15 mg/m3

 

  10 - 15

 

 

 

 

  Viable bacterial cultures

 NA

 NDA

 NDA

  1
 Alkoxylated linear alcohol

 68987-81-5

 NDA

 NDA

 0.5 - 1
 Yucca schidigera leaf extract

  223749-05-1

  NDA

  NDA

   < 1
 *Crystalline silica (quartz)  14808-60-7 

 0.05 mg/m3

 0.05 mg/m3

  < 0.1
 *Ferric oxide   1309-37-1

 10 mg/m3

 5 mg/m3

  < 0.1

 

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3. Hazards Identification

Emergency Overview: The microorganisms used in this product are BioSafety Class 1 microorganisms, as defined by the Centers for Disease Control as unlikely to cause disease in healthy humans or animals. However, persons with compromised immune systems should avoid contact with open wounds and/or breathing dust or mist from manufacturing processes. These organisms are susceptible to many commonly used antibiotics, and Alken-Murray is willing to supply antibiotic sensitivity information to any doctor or import health authority requesting it. Although bacterial cultures included in this product were grown in a sterile aqueous medium containing a variety of nutrients, including corn syrup solids, digests of soybean and/or skim milk, glucose or other sugars, vegetable oils, including olive oil, yeast extract, mineral salts, etc., the concentrations of these residual nutrients are believed to be below those capable of causing more than slight allergic reacftion.

Potential Health Effects:

  • Signs and Symptoms of Acute Overexposure: Direct eye contact may cause strong eye irritation, pain and possible corneal injury. May cause eye infection in immune compromised individuals. Skin contact may cause strong irritation.
  • Signs and Symptoms of Chronic overexposure: Dermatitis and skin sensitization
  • Medical Conditions Generally Aggravated by Exposure: Allergies, dermatitis.
  • Inhalation: (Acute) Inhalation of dust may cause throat irritation and coughing. (Chronic) No effects reported in humans.
  • Ingestion: (Acute) Ingestion may result in abdominal pain, nausea and vomiting.

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4. First Aid Measures

  • Inhalation: Remove patient to fresh air
  • Ingestion: Give patient water or milk to drink to dilute the product. Induce vomiting only if advised by physician or poison control center. Get medical aid for chemical ingredients
  • Skin Contact: Remove contaminated clothing and footwear. Wash skin with soap and water for 15 to 20 minutes. Wash clothing before reuse.
  • Eye Contact: Immediately flush eyes with water for 15 minutes. Get medical attention.
  • Note to Physician: If patient's immune system is compromised, request antibiotic sensitivity information from Alken-Murray Corporation by e-mail: msds@alken-murray.com

 

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5. Fire Fighting Measures

 Flash Point: NA

Flammability Limits: NA

Autoignition temp: NA

Fire Extinguishing Media: Water spray, carbon dioxide, dry chemical

Special Fire-Fighting Information: None

Unusual Fire and Explosion Hazards: None

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6. Accidental Release Measures

For small spills, flush to waste treatment sewer (product is biodegradable). For large spills, contain and collect for reuse. Wear approved respirator for nuisance dust during cleanup.

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7. Handling and Storage

 Store in cool dry place, away from sunlight and temperature extremes. We have now included an inner plastic bag with twist tie seal, to help protect the product. If pail is stored open in moist, warm room, the surfactant in the product will attract moisture sufficient to awaken the surfactant-degrading microbes in the product, which will then reduce overall product effectiveness. Keep pail closed when not scooping out the current dosage, and also keep twist tie sealed on inner bag to prevent this humectant effect from happening, reducing product effectiveness. If the product becomes moistened,add Alken Enz-Odor 2 to your treatment protocol to restore surfactant and enhance overall treatment. Discuss with your distributor for guidance.

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8. Exposure Controls/ Personal Protection

  • Ventilation System: Good general ventilation is advisable
  • Personal Respirators (NIOSH or EN 166 Approved ): if needed, use respirator to screen out nuisance dust
  • Skin Protection: Long sleeved clothing
  • Eye Protection: Safety glasses if dust is raised
  • Other Control Measures: Minimize exposure in accordance with good hygiene practice. Avoid handling which would create large amounts of dust.
\

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9. Physical and Chemical Properties

  • Appearance and Color: Free-flowing tan to brown powder.
  • Odor: Yeast-like odor
  • Solubility in Water: Moderate, contains viable bacteria
  • Specific Gravity: NDA
  • Bulk density: Approximately 0.66-0.77 gm/cm3
  • pH: 6.5 - 8.5
  • % volatile by volume @ 21C (70F): Nil
  • Boiling Point: NA
  • Melting Point: NA
  • Vapor Density (Air=1): NA
  • Vapor Pressure (mm Hg): NA
  • Evaporation Rate (Bu. Acetate=1): NA

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10. Stability and Reactivity

  • Stability: Product is stable.
  • Hazardous Decomposition Products: None
  • Hazardous Polymerization: will not occur.
  • Incompatibility: Acids, alkalies, other toxic materials may inactivate biological cultures.
  • Conditions to Avoid: Incompatible substances

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11. Toxicological Information

  • Toxicological Data:(CFR Title 16, Title 1500.42)
RTECS: Bacterial cultures: 1004274VB / CAS 116469-86-4: 1012301CS/ CAS 7732-18-5: ZC0110000/ CAS# 1317-65-3: EV9580000/ CAS# 56-81-5: MA8050000/ CAS#223749-05-1:NONE / CAS# 68987-81-5: 1007597AL/ / CAS# 14808-60-7:VV7330000/ CAS# 1309-37-1:NO7420000
 
LD50/LC50: CAS# 116469-86-4: this is a natural food substance with no reported ingestion toxicity / CAS# 7732-18-5: LD50= >90 mL/Kg / CAS# 1317-65-3: Oral, rat LD50 = 6450 mg/Kg / CAS# 56-81-5: Oral, mouse LD50 = 4090 mg/Kg; Oral, rat LD50 = 12,600 mg/Kg / CAS# 223749-05-1 (Yucca schidigera) - Oral, mouse, LC50 of a 70% solution = > 5000 mg/kg / CAS# 68987-81-5: Oral, rat LD50 = 1800 mg/Kg; Oral, mouse LD50 = 5,000 mg/Kg; Dermal (rabbit) LD50 = > 2,000 mg/Kg / CAS# 1408-60-7: Oral, rat LD59 = 500 mg/Kg / CAS# 1309-37-1: Oral, rat LD50 = > 5,000 mg/Kg
 
  • Carcinogenicity:
ACGIH-A2 - Crystalline silica, CAS# 14808-60-8 "Suspected Human Carcinogen" List
ACGIH-A4 - Ferric oxide, CAS#1309-37-1 "Suspected Animal Carcinogen" List
IARC-Group 1 - Crystalline silica, CAS# 14808-60-8, "Proven Human Carcinogen" List
NTP - Crystalline silica, CAS# 14808-60-8 - "Human Carcinogen" List,
Other ingredients are NOT found on any lists published by ACGIH, IARC, NIOSH, NTP or OSHA

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12. Ecological Information

Environmental Fate: This product is not likely to bioconcentrate and is unlikely to create any negative environmental impact, other than a slight reduction in oxygen concentration at the site of release.

Environmental Toxicity: Surfactants, including CAS# 68987-81-5, Alkoxylated Linear Alcohol (C7-C10 ), are potentially harmful to aquatic life, making fish gills too slippery to trap oxygen bubbles.

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13. Disposal Considerations

 RCRA Hazard Class (if discarded): Neat, unused product is not considered a hazardous waste, according to RCRA regulations 40 CFR 261. For proper disposal of used materials, an assessment must be completed to determine the proper waste management options permissible under applicable rules, regulations and/or laws governing client's location. Wash containers down with water and disinfect with a 1% sodium hypochlorite solution, triple rinse and dispose of rinse water to sewer. Then remove or deface product label to avoid confusion if pail or drum is later refilled. Clean, empty containers should be recycled or disposed of through an approved waste management facility.

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14. Transportation Information

  • DOT Proper Shipping Name: Not regulated as hazardous by DOT
  • DOT Hazard Class: None
  • DOT Label: Class 60 (item 20400) "Bacteria, sewage or industrial waste treating, in dry or liquid carrier, with or without enzymes in bulk, bags, barrels or pails." Alken Clear-Flo 4000.

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15. Regulatory Information

  • TSCA:  (40CFR 710) All chemical ingredients are listed on the TSCA 8(b) inventory. None of the ingredients are on the Health and Safety Reporting List, are under Chemical Test rule, are listed under TSCA Section 12B, or have a SNUR under TSCA
  • CERCLA Reportable Quantity: This product does NOT contain ingredients that have Reportable Quantity (RQ) requirements under US 40 CFR 117.302
  • Clean Air Act: This formula does not contain any hazardous air pollutants or ozone depletors, nor were such chemicals used during manufacture of ingredients.
  • Clean Water Act: None of the chemicals in this product are listed as hazardous, toxic or priority pollutants.
  • USDA: Alken Clear-Flo 4000 meets product composition requirements for USDA Class L2, use in sewage and/or drain lines of official establishments operating under Federal meat, poultry, shell egg grading, and egg products inspection programs.
  • STATE RIGHT-TO-KNOW LAWS: Glycerine (2.5%), CAS# 56-81-5 IS found on the following RTK lists: Pennsylvania, Minnesota & Massachusetts. Crystalline silica (CAS#14808-60-7) <0.1% of product IS listed on the following RTK lists: California, New Jersey, Pennsylvania, Minnesota & Massachusetts. Ferric oxide, CAS# 1309-37-1, < 0.1% of product IS listed on the following RTK lists: Massachusetts, Minnesota, New Jersey & Pennsylvania. Other ingredients are NOT listed on any of the following state right to know lists: California, Connecticut, Florida, Illinois, Louisiana, Maine, Maryland, Massachusetts, Minnesota, New Jersey, New York, Pennsylvania, Rhode Island or Tennessee.
  • California Proposition 65 Labeling: This product MAY contain TRACE amounts of ethylene oxide (CAS# 75-21-8) or propylene oxide (CAS# 75-56-9) and 1,4 dioxane (CAS# 123-91-1), and contains <0.1% Crystalline Silica (CAS# 14808-60-7), chemicals known to the state of California to cause cancer and/or birth defects and/or reproductive harm.
  • SARA TITLE III:

..................................Section 302/304 Extremely Hazardous Substances: None

..................................Section 311 Hazard Categorization: Acute, chronic

..................................Section 313 Toxic Chemicals: None

  • Canadian DSL: Contains bacterial strains that are NOT listed on the October 2005 version of the Canadian Domestic Substances List. We advise Canadian clients to purchase Alken Clear-Flo 4000C, a powdered formula that IS totally compliant with Canadian-import regulations.
  • Canada's Ingredient Disclosure List: Crystalline silica (CAS#14808-60-7), present at < 0.1% of product and ferric oxide, (CAS#1309-37-1), present at <0.1%, ARE listed on the CIDL. Other ingredients are NOT listed on the CiDL. This MSDS has been prepared according to the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR.

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16. Other Information

Reason for Revision: Routine review & revision

Alken-Murray Corporation provides the information contained herein in good faith, in compliance with the Occupational Safety and Health Act of 1970, but makes no representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Alken-Murray warrants that this product is of merchantable quality. The implied warranty of fitness for a particular purpose is limited to the extent the products are used for the purpose or uses described on the product's label or in any written instructions or materials distributed to the buyer by Alken-Murray and is hereby disclaimed should buyer use the products in a manner inconsistent with this uses or purposes described therein. In no event shall Alken-Murray be liable for any consequential, exemplary, or incidental damages incurred by buyer even if it has been advised of the possibility of such damages.

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E-mail: fog@alken-murray.com

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