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Oxygen Removal Rates of Alken® Treatment J-677 vs. Other Chemicals


Dissolved Oxygen, ppm

Removal of Oxygen versus Time in Minutes

0

15

30

60

90

120
1. Alken® Treatment J-677

8.60

4.70

2.63

1.05

0.54

0.33
 1A.Alken® Treatment J-674
2. N-N-Diethylhydroxylamine (DEHA)

9.70

8.76

8.08

6.50

5.60

5.40
3. Alken® Treatment J-666, (Morpholine) 

9.43

9.26

8.85

8.70

8.61

8.61
3A. Alken® Treatment J-670 (Morpholine) 

4. Cyclohexylamine

Alken® Treatment J-671

9.50

9.03

8.88

8.76

8.66

8.60

5. Diethylaminoethanol (DEAE)

Alken® Treatment J-673

9.86

9.60

9.57

9.50

9.50

9.50
6. Dimethylpropanolamine

9.65

9.04

8.63

8.43

8.39

8.36
7. 2-Amino-2-methyl-1-propanol (AMP)

8.63

8.52

8.45

8.25

8.12

8.12

The tests were performed in the laboratory using a 4.5-liter reaction vessel containing distilled water saturated with dissolved oxygen and 10 ppm carbon dioxide. A 5-gallon batch of distilled water was saturated with oxygen by bubbling air through a fritted dispersion tube. The carbon dioxide was naturally present in the distilled water.


The 4.5-liter container was filled up with the oxygen-saturated water containing 10 ppm carbon dioxide. The water temperature was adjusted at 70.degree..+-.2.degree. F. The level of dissolved oxygen was determined by means of an Orion pH meter, model SA 520 (a commercially available pH meter) equipped with oxygen selective membrane electrode, model 97-08.99, fitted with BOD bottle-top attachment . After calibration, the oxygen probe was inserted into the top of the container.


The first test (#2) was conducted by injecting 36 ppm, N,N-diethylhydroxylamine (DEHA). The subsequent decrease in oxygen concentration was measured as a function of time. Similar experiments were performed by using other neutralizing amines, and with various formulas from Alken-Murray's Treatment-J series, to determine the effect of the individual amines, alone, and the effect of various combination formulas

As you can see in the table above, after 120 minutes, Alken® Treatment J-677 is by far the most powerful oxygen scavenger, especially in low temperature water containing both dissolved oxygen and carbon dioxide. For use in a functioning boiler,with high temperature water, the closely-related formula, Alken® Treatment J-674 delivers oxygen scavenging and corrosion prevention.

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