ALKEN® SOLUTIONS A3040L

Effective Date: 03/29/2007

 Product Bulletin


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 Material Safety Data Sheet
 Manufacturer's Name: Alken-Murray Corporation
 Manufacturer's Address: P.O. Box 400, New Hyde Park, New York 11040
  T: 540-636-1236 Fax: 540-636-1770
  E-mail: msds@alken-murray.com 
 Manufacturer's Cage Code: 2A384
For chemical emergency - spill, leak, fire or accident - call CHEMTREC - day or night - (800) 424-9300 or outside the USA (703) 527-3887

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NFPA Hazard Ratings:

 0=Minimal, 1=Slight, 2=Moderate, 3=Serious, 4=Severe

 Health=1  Fire=1  Reactivity=0

North American Emergency Guidebook: Non-combustible for DOT(Combustible Class IIIB)

 

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All ingredients on Canadian DSL and USA TSCA lists

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 1. Product Identification

 Synonyms:  Solutions A3040L
 CAS Number:  Not applicable to mixtures
 Chemical Formula:  mixture
 Formula ID Codes:  33040

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2. Composition/Information on Ingredients

Ingredients not precisely identified are proprietary and/or non-hazardous per 29 CFR 1910-1200 and/or represent less than 1%. All chemical ingredients appear on the EPA TSCA inventory.
 Chemical Name  CAS Number  OSHA PEL  ACGIH TLV   % Weight
2-propanoic acid, sodium salt, polymer with 2-propenamide  25085-02-3   NDA   NDA   67 - 79
Light, Low Odor Petroleum hydrotreated solvent  64742-47-8  NDA   NDA   20 - 30
Isopropyl alcohol   67-63-0  400 ppm   400 ppm   1 - 3

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 3. Hazards Identification

Emergency Overview: Caution: Irritant to eyes, skin. Heated vapors irritate respiratory tract.

Potential Health Effects:

  • Signs and Symptoms of Acute Overexposure: Eye, skin irritation. Inhalation of heated vapors may irritate the respiratory tract.
  • Signs and Symptoms of Chronic overexposure: Prolonged inhalation of concentrated.heated vapors may cause damage to the kidneys. Reddening and swelling of affected area with possile itching, burning or other discomfort.
  • Medical Conditions Generally Aggravated by Exposure: Existing cuts, rashes, allergies, or other sensitive areas.
  • Ingestion: Ingestion may result in abdominal pain, nausea, and vomiting.

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 4. First Aid Measures

  • Inhalation: Remove victim to fresh air
  • Ingestion: Give victim water or milk to drink to dilute the product. Get medical advice..
  • Skin Contact: Remove contaminated clothing and footwear. Wash skin with soap and water. Wash clothing before reuse.
  • Eye Contact: Immediately flush eyes with water for 15 minutes. Get medical attention.
  • Note to Physician: None

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 5. Fire Fighting Measures

 Flash Point: > 200 degrees F (PMCC)

Flammability Limits: NDA

Autoignition temp: NDA

Fire Extinguishing Media: Any available extinguishing including water spray, carbon dioxide, dry chemical, Halon 1211

Special Fire-Fighting Information: Spilled chemical creates extremely slippery conditions, especially in contact with water. Use caution. Respiratory and eye protection are reqyired. Petroleum component is combustible, if separated from other ingredients. Vapors/fumes will ignite.

Unusual Fire and Explosion Hazards: Hydrocarbon components are combustible if separated from the emulsion.

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 6. Accidental Release Measures

Remove sources of ignition. Contain and collect, using a suitable absorbent, if needed. Place into suitable container(s) for disposal. Thoruhgly flush residuals to drain, as spilled product creates extremely slippery conditions.

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 7. Handling and Storage

 Handle as an irritant. Do not get in eyes. Avoid prolonged/repeated skin contact. Do not inhale vapors/mists. Do not ingest. Store away from sources of ignition. Spilled product creates very slippery condition, especially in contact with water.

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 8. Exposure Controls/ Personal Protection

  • Ventilation System: Good general ventilation is advisable. Local exhaust desired.
  • Personal Respirators (NIOSH Approved): None required for normal use and processes. if needed, use respirator to filter out mists/vapors.
  • Skin Protection: Long sleeved clothing, impervious rubber or neoprene gloves and protective apron.
  • Eye Protection: Safety glasses or goggles
  • Other Control Measures: Minimize exposure in accordance with good hygiene practice. Avoid handling which would create large amounts of mists/vapors. Exxon Medical Research recommended inhalation TLV for CAS 64742-47-8 of 200 ppm.

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 9. Physical and Chemical Properties

  • Appearance and Color: Milky-white emulsion.
  • Odor: Mild petroleum and acrylate
  • Solubility in Water: Soluble to a maximum concentration of 1% (approximately)
  • Specific Gravity: 1.07
  • Viscosity at 28 deg. C: 2400- 3200 cps
  • % volatile by volume @ 21C (70F): NDA
  • Boiling Point: > 210 degrees F
  • Melting Point: < 23 degrees F
  • Freezing Point: - 15 degrees C
  • Vapor Density (Air=1): > 1
  • Vapor Pressure (mm Hg): < 30
  • Evaporation Rate (Bu. Acetate=1): < 1

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 10. Stability and Reactivity

  • Stability: Product is stable.
  • Hazardous Decomposition Products: None known
  • Hazardous Polymerization: will not occur.
  • Incompatibility: Strong oxidizers: liquid chlorine, concentrated oxygen, sodium hypochlorite, calcium hypochlorite
  • Conditions to Avoid: Incompatible substances

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 11. Toxicological Information

  • Toxicological Data:
RTECS: CAS#25085-02-3: 1011973HP/CAS#64742-47-8: CA5504000 / CAS# 67-63-0: NT8050000
 
LD50 /LC50: CAS# 25085-02-3: Oral, rat LD50 = > 5,000 mg/Kg/ CAS# 67-63-0: Oral, mouse: LD50 = 3600 mg/kg; Oral, rabbit: LD50 = 6410 mg/kg; Oral, rat: LD50 = 5045 mg/kg; Skin, rabbit = 12800 mg/kg./ CAS# 64742-47-8: Oral,rat LD50 = 5 g/Kg
  • Carcinogenicity:
IARC Group 3 - Isopropyl alcohol, CAS# 67-63-0, "Confirmed Animal Carcinogen". Isopropyl alcohol are NOT present on ACGIH, NIOSH, NTR or OSHA carcinogenicity lists
Other Ingredients not listed by ACGIH, IARC, NIOSH, NTR, or OSHA

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 12. Ecological Information

  • Environmental Fate: There is no possibility for this product to bioaccumulate. This product's high molecular weight renders microbial attack very difficult, so it is recalcitrant to microbial degradation, until UV light breaks it down through photolysis into oligomers, which are bioavailable for microbial mineralization. Both acrylamide and sodium acrylate are readily biodegradable under aerobic condions, to 90% within 25 days. IF it is ever considered important to bioremediate the petroleum solvent in this polymer, use Alken Clear-Flo 7008, a selected consortium of live-culture bacteria that target industrial wastewater chemicals, including petroleum hydrocarbons.
  • Aquatic Toxicology:
  • Toxicity to Fish:
LC50 Brachydanio rerio/96 hours =357 mg/L
LC50 Brachydanio rerio/96 hours =178 mg/L
  • Toxicity to Daphnia
EC50/Daphnia Magna/48 hours= 212 mg/L
  • Toxicity to Algae
EC50/Chlorella vulgaris/96 hours= 1,000 mg/L
No observed Effect Concentration = 708 mg/L
  • Toxicity to Bacteria
EC10/Pseudomonas putida/18 hours = 127 mg/L
EC50/Pseudomonas putida/18 hours = 892 mg/L

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 13. Disposal Considerations

 RCRA Hazard Class (if discarded): Non-hazardous liquid waste may be incinerated, according to local state and federal regualtions.

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14. Transportation Information

  • DOT Proper Shipping Name: Not regulated as hazardous by DOT or Canadian TDG
  • DOT Hazard Class: None
  • DOT Label: Class 60:(NMFC item #4612, LTL) "adhesives, adjuvents, spreaders, sliders, liquid, in pails or drums" Alken Solutions A3040L, anionic acrylamide polymer liquid

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 15. Regulatory Information

  • TSCA: : (40CFR 710) All chemical ingredients are listed on the TSCA 8(b) inventory. None of the ingredients are on the Health and Safety Reporting List, are under Chemical Test rule, are listed under TSCA Section 12B, or have a SNUR under TSCA
    CERCLA Reportable Quantity: This product does NOT contain ingredients that have Reportable Quantity (RQ) requirements under US 40 CFR 117.302
  • SARA TITLE III:

    Section 302/304 Extremely Hazardous Substances: None

    Section 311 Hazard Categorization: None

    Section 313 Toxic Chemicals: None 

  • Clean Water Act: None of the chemicals in this formula are listed as Priority Pollutants under CWA.
  • Clean Air Act : Ingredients not listed as hazardous pollutants under CAA. This product does not contain any Class 1 or Class 2 ozone depletors, nor was it made with such chemicals.
  • OSHA: None of the ingredients are considered Extremely Hazardous by OSHA.
  • STATE RIGHT-TO-KNOW lists: Isopropyl alcohol, CAS# 67-63-0 (< 2%) is listed on the following RTK lists: California, New Jersey, Florida, Pennsylvania, Minnesota & Massachusetts. Other ingredients are NOT listed on any of the following state right to know lists: California, Connecticut, Florida, Illinois, Louisiana, Maine, Maryland, Massachusetts, Minnesota, New Jersey, New York, Pennsylvania, Rhode Island or Tennessee.
  • Not subject to California Proposition 65 labeling requirements
  • Canadian WHMIS Classification: CAS 64742-47-8: B3. Combustible Liquid, but flash point of formulated product has a flash pint above flammable-combustible limit for Canada
  • Canadian DSL: all ingredients listed and compliant
  • Canada's Ingredient Disclosure List: Light hydrotreated kerosine solvent CAS# 64742-47-8, comprising 25% of this product IS listed on the CIDL, but other ingredients are "NOT CONTROLLED". This MSDS has been prepared according to the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR.
  • TDG Classification: Not regulated as hazardous by Canadian TDG.
  • IHT Codes: 3906.90.5000

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16. Other Information

Reason for Revision: Routine review & revision

Alken-Murray Corporation provides the information contained herein in good faith, in compliance with the Occupational Safety and Health Act of 1970, but makes no representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Alken-Murray warrants that this product is of merchantable quality. The implied warranty of fitness for a particular purpose is limited to the extent the products are used for the purpose or uses described on the product's label or in any written instructions or materials distributed to the buyer by Alken-Murray and is hereby disclaimed should buyer use the products in a manner inconsistent with this uses or purposes described therein. In no event shall Alken-Murray be liable for any consequential, exemplary, or incidental damages incurred by buyer even if it has been advised of the possibility of such damages.

E-mail: polymer@alken-murray.com

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