ALKEN® SOLUTIONS C133K

Effective Date: 01/05/2007

 Product Bulletin


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 Material Safety Data Sheet
 Manufacturer's Name: Alken-Murray Corporation
 Manufacturer's Address: P.O. Box 400, New Hyde Park, New York 11040
  T: 540-636-1236 Fax: 540-636-1770
  E-mail: msds@alken-murray.com 
 Manufacturer's Cage Code: 2A384
For chemical emergency - spill, leak, fire or accident - call CHEMTREC - day or night - (800) 424-9300 or outside the USA (703) 527-3887

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NFPA Hazard Ratings:

 0=Minimal, 1=Slight, 2=Moderate, 3=Serious, 4=Severe

 Health=1  Fire=1  Reactivity=0

 

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All ingredients on Canadian DSL and USA TSCA lists

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 1. Product Identification

 Synonyms:  Solutions K133L
 CAS Number:  Not applicable to mixtures
 Chemical Formula:  mixture
 Formula ID Codes:  30133

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2. Composition/Information on Ingredients

 

Ingredients not precisely identified are proprietary and/or non-hazardous. All chemical ingredients appear on the EPA TSCA inventory.

 Chemical Name  CAS Number  OSHA PEL  ACGIH TLV   % Weight
Cationic Acrylamide copolymer  69418-26-4   NDA   NDA   20 - 45
Light, Low Odor Petroleum hydrotreated solvent  64742-47-8  NDA   NDA   20 - 30
 Polyoxyethylene 23 Laurel Ether   9002-92-0  NDA  NDA   1- 3

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 3. Hazards Identification

Emergency Overview: Caution: Irritant to eyes, skin. Heated vapors irritate respiratory tract.

Potential Health Effects:

  • Signs and Symptoms of Acute Overexposure: Eye, skin irritation. Inhalation of heated vapors may irritate the respiratory tract.
  • Signs and Symptoms of Chronic overexposure: Prolonged inhalation of concentrated.heated vapors may cause damage to the kidneys. Reddening and swelling of affected area with possile itching, burning or other discomfort.
  • Medical Conditions Generally Aggravated by Exposure: Existing cuts, rashes, allergies, or other sensitive areas.
  • Ingestion: Ingestion may result in abdominal pain, nausea, and vomiting.

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 4. First Aid Measures

  • Inhalation: Remove victim to fresh air
  • Ingestion: Give victim water or milk to drink to dilute the product. Get medical advice..
  • Skin Contact: Remove contaminated clothing and footwear. Wash skin with soap and water. Wash clothing before reuse.
  • Eye Contact: Immediately flush eyes with water for 15 minutes. Get medical attention.
  • Note to Physician: None

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 5. Fire Fighting Measures

 Flash Point: > 212 degrees F (PMCC)

Flammability Limits: NDA

Autoignition temp: NDA

Fire Extinguishing Media: Carbon dioxide, dry chemical, Halon 1211, water

Special Fire-Fighting Information: Spilled chemical creates extremely slippery conditions, especially in contact with water. Use caution. Respiratory and eye protection are reqyired. Petroleum component is combustible, if separated from other ingredients. Vapors/fumes will ignite.

Unusual Fire and Explosion Hazards: None

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 6. Accidental Release Measures

Contain and collect, using a suitable absorbent if needed (sand, earth or vermiculite). Flush residuals to drain with water for normal biological water treatment. Place collected material into suitable containers for disposal. Can usually be disposed of my approved metered release to WWTP or other approved disposal. Observe local, federal and state disposal regulations. Several washes and/or the use of detergents may be necessary to completely clean any spills.

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 7. Handling and Storage

 Handle as an irritant. Do not get in eyes. Avoid prolonged/repeated skin contact. Do not inhale vapors/mists. Do not ingest. Store away from sources of ignition. Spilled product creates very slippery condition, especially in contact with water.

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 8. Exposure Controls/ Personal Protection

  • Ventilation System: Good general ventilation is advisable. Local exhaust desired.
  • Personal Respirators (NIOSH Approved): None required for normal use and processes. if needed, use respirator to filter out mists/vapors.
  • Skin Protection: Long sleeved clothing, impervious rubber or neoprene gloves and protective apron.
  • Eye Protection: Safety glasses or goggles
  • Other Control Measures: Minimize exposure in accordance with good hygiene practice. Avoid handling which would create large amounts of mists/vapors. Exxon Medical Research recommended inhalation TLV for CAS 64742-47-8 of 200 ppm.

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 9. Physical and Chemical Properties

  • Appearance and Color: Milky-white emulsion.
  • Odor: Mild petroleum and acrylate
  • Solubility in Water: Miscible. Highly viscous solutions limit solubility
  • Specific Gravity: Approx. 1.04
  • Viscosity at 28 deg. C: 2400- 4000 cps
  • % volatile by volume @ 21C (70F): NDA
  • Boiling Point: NDA
  • Melting Point: 5 degrees F
  • Freezing Point: - 15 degrees C
  • Vapor Density (Air=1): > 1
  • Vapor Pressure (mm Hg): NDA
  • Evaporation Rate (Bu. Acetate=1): < 1

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 10. Stability and Reactivity

  • Stability: Product is stable.
  • Hazardous Decomposition Products: None known
  • Hazardous Polymerization: will not occur.
  • Incompatibility: Strong oxidizers: liquid chlorine, concentrated oxygen, sodium hypochlorite, calcium hypochlorite
  • Conditions to Avoid: Incompatible substances

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 11. Toxicological Information

  • Toxicological Data:
RTECS: CAS# 69418-26-4:AS3700000/ CAS#64742-47-8: CA5504000/ CAS 9002-92-0:JR5960000, JR5970000, MD0875000
Potential Eye Effects: A primary eye irritation study in rabbits was conducted (using EPA guidelines No. 81-4) using a test material similar to that represented by this MSDS. The results indicated the test material was rated as moderately irritating. "Positive corneal involvement persisted through day 21; therefore the test material was assigned to Toxicity Category I.
Potential Effects of Skin Contact: A primary dermal irritation study in rabbits was conducted (using EPA guidelines No. 81-5) using a test material similar to that represented by this MSDS Test results indicated a primary irritation index of 4.1 out of a possible 8.0, or a descriptive rating of moderately irritating. Based on 72 hour score only, the test material was assigned to Toxicity Category II (severe irritation). This product contains a surfactant which may result in the development of inflammatory changes in the lung, based on studies with rabbits, in which the undiluted surfactant was kept in sustained, occluded contact with the rabbit's skin. See specific LD50 information below for the surfactant in question, which is present below 3% of polymer formula.
LD50 /LC50: CAS# 9002-92-0:Oral, rat LD50 = 1,000 mg/Kg, Oral, mouse LD50 = 1170 mg/Kg; CAS#69418-26-4: Oral,rat LD50 = 5,000 mg/Kg, Dermal rabbit, non-irritating even at high dosages.
  • Carcinogenicity: Not listed by ACGIH, IARC, NIOSH, NTR, or OSHA

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 12. Ecological Information

  • Environmental Fate: The product is rapidly eliminated from the aquatic medium through irreversible adsorption onto suspended matter and dissolved organics
  • Environmental Toxicity: Ingredients are toxic to fish, unless adsorbed onto humic or organic matter.

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 13. Disposal Considerations

 RCRA Hazard Class (if discarded): Neat, unused product is not considered a hazardous waste, according to RCRA regulations 40 CFR 261. . For proper disposal of used materials, an assessment must be completed to determine the proper waste management options permissible under applicable rules, regulations and/or laws governing client's location. Use until less than 1 inch remains in the container, triple rinse with clean water, and pour rinse water to sewer. Then remove or deface product label to avoid confusion if pail or drum is later refilled. Clean, empty containers should be recycled or disposed of through an approved waste management facility.

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14. Transportation Information

  • DOT Proper Shipping Name: Not regulated as hazardous by DOT or Canadian TDG
  • DOT Hazard Class: None
  • DOT Label: Class 60:(NMFC item #4612, LTL) "adhesives, adjuvents, spreaders, sliders, liquid, in pails or drums" Alken Solutions C133K, cationic polyquaternary polymer liquid

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 15. Regulatory Information

  • TSCA: : (40CFR 710) All chemical ingredients are listed on the TSCA 8(b) inventory. None of the ingredients are on the Health and Safety Reporting List, are under Chemical Test rule, are listed under TSCA Section 12B, or have a SNUR under TSCA
    CERCLA Reportable Quantity: This product does NOT contain ingredients that have Reportable Quantity (RQ) requirements under US 40 CFR 117.302
  • SARA TITLE III:

    Section 302/304 Extremely Hazardous Substances: None

    Section 311 Hazard Categorization: None

    Section 313 Toxic Chemicals: None 

  • Clean Water Act: This product is considered an oil under Section 311 of the Clean Water Act (40 CFR 110) and the Oil Pollution Act of 1990. Discharges that produce a visible sheen on surface waters or on waterways or sewers that lead to surface water must be reported to the National Response Center, 800-424-8802. Product can be bioremediated with Alken Clear-Flo 7008.
  • Clean Air Act : Ingredients not listed as hazardous pollutants under CAA. This product does not contain any Class 1 or Class 2 ozone depletors, nor was it made with such chemicals.
  • OSHA: None of the ingredients are considered Extremely Hazardous by OSHA.
  • STATE RIGHT-TO-KNOW LAWS:. Ingredients not listed on California, Connecticut, Florida, Illinois, Louisiana, Massachusetts, New Jersey, New York, Pennsylvania, or Rhode Island.
  • Not subject to California Proposition 65 labeling requirements
  • Canadian WHMIS Classification: CAS 64742-47-8: B3. Combustible Liquid, but flash point of formulated product has a flash pint above flammable-combustible limit for Canada
  • Canadian DSL: all ingredients listed and compliant
  • Canada's Ingredient Disclosure List: Light hydrotreated kerosine solvent CAS# 64742-47-8, comprising 25% of this product IS listed on the CIDL, but other ingredients are "NOT CONTROLLED". This MSDS has been prepared according to the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR.
  • TDG Classification: Not regulated as hazardous by Canadian TDG.
  • IHT Codes: 3906.90.5000

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16. Other Information

Reason for Revision: Routine review & revision

Alken-Murray Corporation provides the information contained herein in good faith, in compliance with the Occupational Safety and Health Act of 1970, but makes no representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Alken-Murray warrants that this product is of merchantable quality. The implied warranty of fitness for a particular purpose is limited to the extent the products are used for the purpose or uses described on the product's label or in any written instructions or materials distributed to the buyer by Alken-Murray and is hereby disclaimed should buyer use the products in a manner inconsistent with this uses or purposes described therein. In no event shall Alken-Murray be liable for any consequential, exemplary, or incidental damages incurred by buyer even if it has been advised of the possibility of such damages.

E-mail: polymer@alken-murray.com

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