NFPA Hazard Ratings:

*New Jersey Trade Secret # 00850201001-5285P (Telomer B monoether with PEG)

Ingredients not precisely identified are proprietary and/or non-hazardous per 29 CFR 1910-1200 and/or represent less than 1%... All chemical ingredients appear on the EPA TSCA inventory.

• Signs and Symptoms of Acute Overexposure: Contact with liquid, mist, or vapor can cause immediate irritation or corrosive burns to all human tissue. Severity of the burn is generally determined by the concentration of the solution and duration of exposure. Contact with eyes may result in permanent visual loss unless removed quickly by thorough irrigation with water. Inhalation of concentrated vapor or mist will damage upper respiratory tract and lung tissues. Swallowing may be fatal. May be absorbed through the skin in harmful amounts
• Signs and Symptoms of Chronic overexposure: Repeated exposure may cause chronic bronchitis or respiratory inflammation and erosion of teeth. Repeated skin contact with dilute solutions may cause dermatitis. Repeated eye contact may cause conjunctivitis and photosensitization.
• Medical Conditions Generally Aggravated by Exposure: NDA
• Other Comments: NDA

• Inhalation: Remove patient to fresh air. Get prompt medical attention
• Ingestion: Do not induce vomiting. Give patient large amounts of milk or water to drink. Get patient to hospital promptly.
• Skin Contact: Remove contaminated clothing and footwear. Wash skin for 15 minutes with soap and water. Wash clothing before reuse. If irritation persists, get medical attention.
• Eye Contact: Immediately flush eyes with water for 15 minutes. Forcibly hold eyelids apart to ensure complete irrigation of eye and eyelid tissue. Do not allow patient to rub or keep eyes closed. Get immediate medical attention.
• Note to Physician: Treat symptomatically. No specific antidote.

Flash Point: 1782 degrees C (3,239.60 degrees F) by Pensky-Martens Closed Cup method, ASTM D-93

Flammability Limits: NDA

Autoignition temp: NDA

Fire Extinguishing Media: Suitable for the surrounding fire

Special Fire-Fighting Information: Wear NIOSH-approved SCBA (Self-Contained Breathing Apparatus). Use water spray to cool containers.

Unusual Fire and Explosion Hazards: Reacts with reactive metals (potassium, sodium, calcium, powdered aluminum, zinc, magnesium) to produce flammable hydrogen gas.

• Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
• Personal Respirators (NIOSH or EN 166 Approved): Use approved full face respirator with canister approved for hydrochloric acid vapor or mist. Consult respirator manufacturer to determine appropriate equipment. If concentrations are high or unknown, use self-contained breathing apparatus.
• Skin Protection: Rubber gloves, boots and apron. Body covering clothing to minimize exposure
• Eye Protection: Splash-proof chemical safety goggles, full face shield. Do not wear contact lenses. Recommend eyewash fountain nearby where product is handled in concentrated form (LRSD 890 contains < 10% concentration).
• Other Control Measures: A source of clean water should be available in the work area or flushing eyes and skin.

ACGIH: CAS 5329-14-6: 1 mg/m3

NIOSH: 50 ppm IDLH
OSHA Final PELs: C 5 ppm; C 7 mg/m3.
OSHA Vacated PELs: No vacated PELs listed for this product.

• Appearance and Color: Brown water-thin liquid
• Odor: Sharp, pungent, irritating odor
• Solubility in Water: 100%
• Specific Gravity: 1.05
• Density Lbs/Gal: 8.75
• pH: (1%) < 1.0 (acidic)
• % volatile by volume @ 21C (70F): 85% weight by volume
• Boiling Point: 215 degrees F (102 degrees C)
• Freezing Point: 30 degrees F (-1 degrees C)
• Melting Point: NDA
• Vapor Density (Air=1): = 100 C (212 F)
• Vapor Pressure (mm Hg): = water
• Evaporation Rate (Bu. Acetate=1): = < 1

• Stability: Product is stable under normal conditions of storage and handling. In water solution, slowly hydrolyzes to form ammonium sulfate and bisulfate.
• Hazardous Decomposition Products: Chlorine gas may be released when product is mixed with strong oxidizers. Hydrogen chloride, carbon dioxide, carbon monoxide.
• Hazardous Polymerization: has not been reported
• Incompatibility: Substance polymerizes on contact with aldehydes or epoxides. Reactions with alkalies and active metals generate great deal of heat. Mixing with strong oxidizers can produce poisonous gas. Avoid open flames or sparks.
• Conditions to Avoid: Incompatible chemicals

• Toxicological Data: (CFR Title 16)

RTECS: CAS# 7732-18-5: ZC0110000 / CAS# 7647-01-0: MW4025000 / CAS# 105-55-5: YS98000000 / CAS# 100-97-0: MN4725000 / CAS# 10043-52-4:EV9810000 / CAS# 57-55-6: TY2000000 / CAS# 7664-38-2: TB6300000 / CAS# 67-63-0: NT8050000 / CAS# 65545-80-4:TR1581533 / CAS# 107-19-7: UK5075000

LD50 /LC50: CAS# 77732-18-5: LD50= >90 mL/Kg / CAS# 7647-01-0:Oral, mouse LD50 = 1108 ppm/1H; Oral, rabbit LD50 = 900 mg/Kg; / CAS# 105-55-5: Oral, rat LD50 = 316 mg/Kg; Oral, mouse LD50 = 681 mg/Kg / CAS# 100-97-0: Oral, rat LD50 = 9200 mg/Kg / CAS# 10043-52-4: Oral, mouse LD50 = 1940 mg/Kg; Oral, rat LD50 = 1 g/Kg / CAS# 57-55-6: Oral, rat LD50 = 20 g/Kg / CAS# 7664-38-2: Oral, mouse LD50 = 1.25 g/Kg; Oral, rat LD50 = 1530 mg/Kg / CAS# 67-63-0: Oral, mouse: LD50 = 3600 mg/kg; Oral, rabbit: LD50 = 6410 mg/kg; Oral, rat: LD50 = 5045 mg/kg; Skin, rabbit = 12800 mg/kg. / CAS# 65545-80-4: Oral, mouse LD50 = 1700 mg/Kg / CAS# 107-19-7: Oral, rat LD50 = 20 mg/Kg; Oral, mouse LD50 = 50 mg/Kg

• Carcinogenicity:

IARC-Group 3: Isopropyl alcohol, CAS# 67-63-0, "confirmed animal carcinogen", but NOT listed on ACGIH, NIOSH, NTR or OSHA lists.

Other Ingredients are not listed as carcinogens by ACGIH, IARC, NIOSH, NTR, or OSHA

• Environmental Fate: This substance will neutralize soil carbonate-based compounds in the environment. If undiluted product is released into natural water bodies, test pH and adjust alkalinity to offset introduction of Alken LRSD 890.
• Environmental Toxicity: CAS 7647-01-0: Trout LC100=10 mg/L/24H Shrimp LC50=100-330 ppm Starfish LC50=100-330mg/L/48H Shore crab LC50=240 mg/L/48H Chronic plant toxicity=100 ppm Fish-toxicity LC50:862 mg/l. Can cause a serious pH drop if not thoroughly diluted or neutralized prior to dispensing into sewer system or other body of water

• DOT Proper Shipping Name: Corrosive Liquid Solution (Contains Hydrochloric acid, solution) Class 8, UN 1789, PG II
  
  DOT Hazard Class: 8 (Corrosive)
• UN/NA ID Number: 1789
• Packing Group: II
• DOT Label: Corrosive Liquid Solution (Contains Hydrochloric acid, solution) Class 8, UN 1789, PG II
  

• TSCA: (40CFR 710) All chemical ingredients are listed on the TSCA 8(b) inventory. None of the ingredients are on the Health and Safety Reporting List, are under Chemical Test rule, are listed under TSCA Section 12B, or have a SNUR under TSCA
• CERCLA Reportable Quantity: (40CFR 302.4) 5,000 lbs. of hydrochloric acid (1500 gal of product)
  
• SARA TITLE III:

..................................Section 302/304 Extremely Hazardous Substances: Final RQ = 5,000 lbs.; TPQ = 500 lbs; RQ = 5,000 lbs (dos not meet toxicity criteria because of high production volume and recognized toxicity is considered a chemical of concern.

..................................Section 311 Hazard Categorization: Acute Health, Delayed Health, Chronic Health

..................................Section 313 Toxic Chemicals: Hydrochloric acid is subject to the reporting requirements of Section 313 of SARA title III and 40 CFR part 373

• Clean Air Act: Hydrochloric acid IS listed as a hazardous air pollutant (HAP), but does not contain ozone depletors, nor was it made from such chemicals..
• Clean Water Act: Hydrochloric acid IS listed as a hazardous substance under CWA
• OSHA: Hydrochloric acid & Hexamine ARE BOTH LISTED as "Extremely Hazardous" by definition of Hazard Communication Standard (29CFR 1910.1200).
• STATE RIGHT-TO-KNOW LISTS: Hydrochloric acid, CAS# 7647-01-1,(9.6%) can be found on the following state RTK lists: California, Connecticut, Florida, Illinois, Louisiana, Massachussetts, Maine, Minnesota,New Jersey, Pennsylvania, & Rhode Island. N, N'-Diethylthiourea, CAS# 105-55-5 (< 1%) IS listed on the Massachusetts RTK list. CAS# 100-97-0, Hexamine (<1%) ARE listed on the following RTK list: New Jersey. Isopropyl alcohol, CAS# 67-63-0 (< 1%) is listed on the following RTK lists: California, New Jersey, Florida, Pennsylvania, Minnesota & Massachusetts. Propargyl alcohol, CAS# 107-19-7 (<1%) IS found on the following RTK lists: Florida, Massachusetts, Minnesota, New Jersey, New York, Rhode Island, & Tennessee. Other ingredients are NOT listed on the following RTK lists: California, Florida, Illinois, Louisiana, Maine, Maryland, Massachusetts, Minnesota, New Jersey, New York, Pennsylvania, Rhode Island or Tennessee.
• Not subject to California Proposition 65 labeling requirements (California)
• Canadian DSL: Chemical ingredientsARE ALL listed on Canada's DSL list. Product is authorized for sale in Canada
• Canada's Ingredient Disclosure List: Hydrochloric acid (CAS# 7647-01-1), representing 9.6% of product, CAS# 100-97-0, Hexamine, representing < 1% of this product and CAS# 107-19-7, Propargyl alcohol, representing <1% of this product ARE listed on the CIDL, but other ingredients in this product are not present on the CIDL. This MSDS has been prepared according to the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR.
• Canadian WHMIS: Class E - "corrosive" & Class D2B "Other Toxic Effects"
• TDG Classification: Corrosive Liquid Solution (Contains Hydrochloric acid, solution) Class 8, UN 1789, PG II

16. Other Information

Reason for Revision: Routine review & revision

Alken-Murray Corporation provides the information contained herein in good faith, in compliance with the Occupational Safety and Health Act of 1970, but makes no representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Alken-Murray warrants that this product is of merchantable quality. The implied warranty of fitness for a particular purpose is limited to the extent the products are used for the purpose or uses described on the product's label or in any written instructions or materials distributed to the buyer by Alken-Murray and is hereby disclaimed should buyer use the products in a manner inconsistent with this uses or purposes described therein. In no event shall Alken-Murray be liable for any consequential, exemplary, or incidental damages incurred by buyer even if it has been advised of the possibility of such damages.